Volume 136
Main Index

Issue 1, Pages 1-138 (16 August 1977)

X-ray structures of the dimeric dimethylthallium(III) Derivatives, [(CH3)2TlX]2 (X = OC6H5, OC6H4Cl-o, SC6H5; relevance of 1J(205Tl- 13C) and 2J(205Tl---1H) as structural probes Pages C7-C10 P. J. Burke, L. A. Gray, P. J. C. Hayward, R. W. Matthews, M. McPartlin, D. G. Gillies

Reaction of acetylenes with transition metals : X. A stable σ-butadienylpalladium complex derived from Phenylmesitylacetylene and dichlorobis(benzonitrile)palladium Pages C15-C17 Ilie G. Dinulescu, Sorin Staicu, Eliza Avram, Filip Chiraleu, Margaret Avram

A chelate methldisulphido-ligand from methylation of co-ordinated disulphur. Structure of [Os(η2-S2Me) (CO)2 (PPh3)2]ClO4 Pages C1-C3 G. R. Clark, D. R. Russell, W. R. Roper and, A. Walker

Cyclopentadienyl-niobium and -tantalum chemistry; x-ray structures of {(η-C5H5)NbCl3[(C6H5)2P(C6H5)2]}, C6H5CH3 Pages C4-C6 Jean-Claude Daran, Andre de Cian, Malcolm L. H. Green, Nauser Siganporia

Komplexchemie reaktiver organischer verbindungen : XVIII. Halogencyclopentadienyl---eisen-komplexe vom Typ (η-C5 H5-nXnFe(CO)2 (σ-C3F7 Pages C11-C14 Wolfgang A. Herrmann, Michael Huber

A convenient synthesis of Alkyltetramethylcyclopentadienes and Phenyltetramethylcyclopentadiene Pages 1-5 Richard S. Threlkel, John E. Bercaw

Ambident nucleophiles : V. Mercury(II) derivatives of diethyl malonate, ethyl acetoacetate, ethyl cyanoacetate, and malononitrile Pages 7-12 C. Glidewell

The chemistry and the sterechemistry of Poly(N-Alkyliminoalanes : XIII. The crystal and molecular structure of the hexamers (ClAlN-i-Pr)6 and (Me0.83H0.17AlN-i-Pr)6MeAlN-i-Pr)6 Pages 13-18 G. Del Piero, G. Perego, S. Cucinella, M. Cesari, A. Mazzei

Thermodynamics of metal---ligand bond formation : XXVIII. Lewis acidity of organotin carboxylates and isocyanates Pages 19-24 D. P. Graddon, B. A. Rana

Über silicium---schwefel-verbindungen : III. Neue organylthiosilane Pages 25-31 Dietmar Brandes

Determination of the π barrier to rotation of the Carbonyl group in para-dimethylamino-π-(tricarbonylchronium) Benzaldehyde by 13C NMR spectroscopy Pages 33-37 B. P. Roques

Cyanoalkyl derivatives of manganese(I) and iron(I) Carbonyls Pages 39-43 Tristano Boschi, Giancarlo Campesan, Renzo Ros, Raymond Roulet

Basicity of transition metal carbonyl complexes : XI. Reactions of C5H5Mn(CO)2L with stannic chloride and structure of reaction products Pages 45-55 A. G. Ginzburg, N. G. Bokyi, A. I. Yanovsky, Yu. T. Struchkov, V. N. Setkina, D. N. Kursanov

Electronic effects in the cyclopentadienyl ring. The 13C NMR spectraof monosubstituted ferrocenes Pages 57-63 A. A. Koridze, P. V. Petrovskii, A. I. Mokhov, A. I. Lutsenko

The 13C NMR spectra and structure of ferrocenylcarbenium ions Pages 65-71 A. A. Koridze, P. V. Petrovskii, S. P. Gubin, V. I. Sokolov, A. I. Mokhov

Homogenous catalysis : V. Hydrosilyation of dienes with octacarbonyldicobalt(0) Pages 73-85 Andrew J. Cornish, Michael F. Lappert, Terence A. Nile

Pentamethylcyclopentadienyl-rhodium and -iridium complexes XV. Cationic complexes with tertiary phosphines and phosphites and their rearrangements reactions Pages 87-93 Stephen J. Thompson, Colin White, Peter M. Maitlis

The reactions of nickel(II) carboxylates with a series of ethylaluminum chlorides Pages 95-102 B. T. Pennington, J. E. Howell

Chimie organometallique VIII. Reaction des organocuprates avec les acetates allyliques. Existence probable de complexes π-allyliques du cuivre Pages 103-110 J. Levisalles, M. Rudler-Chauvin, H. Rudler

Oxidative coupling of isobutene with vinylidene chloride by palladium (II) Salts Pages 111-120 David Holland, David J. Milner, Hugh W. B. Reed

Further studies on the 1,4 addition reaction of hexafluorobut-2-yne to rhodium(I)-β-ketoenolate rings and related systems Pages 121-138 Alan C. Jarvis, Raymond D. W. Kammitt

Issue 2, Pages 139-279 (23 August 1977)

Reactions of (η5-C5H5)Fe(CO)2(η1-C5H5) with phosphorus donor ligands Pages c31-c36 Jay A. Labinger

Heteroferrocene : II. Das 2,2-dimethyl-bis(thiopheno(b))ferrocen Pages c27-c30 Heinrich Volz, Heinrich Kowarsch

Mixed-metal hydride complexes containing Zr---H---A1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides Pages c19-c22 Larry I. Shoer, Kerrie I. Gell, Jeffrey Schwartz

Erratum Page c40

“Topics in sulfur chemistry” : Vol. 2, A. Senning, ed.,; “Carbon Sulfides and their Inorganic and Complex Chemistry”, by G. Gattow and W. Behrendt, Georg Thieme Verlag, Stuttgart, vi + 261 pages, 1977, DM 128. Page c37 Robert J. Angelici

Importance of cationic assistance in the reactions of M[(η5-C5H5)Fe(CO)2]salts with epoxides Pages c23-c26 Miriam Nitay, Myron Rosenblum

“Topics in phosphorus chemistry” : E. J. Griffiths and M. Grayson, editors, John Wiley & Sons, Inc., New York/London/Sydney/Toronto, Vol. 8, 1976, viii + 611 pages, $ 52.00, £ 30.70, and Volume 9, 1977, vii + 516 pages, $ 55.00 £ 32.65. Pages c38-c39 Dietmar Seyferth

Metalation reactions : III. The action of n-butyllithium on 1,3-benzodioxole and 1,3-benzoxathiole derivatives Pages 139-146 S. Cabiddu, A. Maccioni, P. P. Piras, M. Secci

The enthalpies of protonation of propenyllithiums, phenyllithium, and ethyllithium Pages 147-159 Gaylen R. Brubaker, Peter Beak

Photoelectron spectra of substituted dialkylphenylthioboranes Pages 161-168 F. Bernardi, R. Danieli, G. Distefano, A. Modelli, A. Ricci

Behaviour of 2,2′-bipyridyl towards methylethyl- and n-propyl-(n-butyl)-tin dichlorides in nitrobenzene Pages 169-171 K. L. Jaura, K. Lal

Investigations on organoantimony compounds : XVI. Preparation and properties of heterocyclic trichloro-cis-diorganoantimony(V) compounds and of the corresponding tetramethylammonium tetrachlorodiorganoantimonates Pages 173-184 H. A. Meinema, H. F. Martens, J. G. Noltes, N. Bertazzi and, R. Barbieri

A 19F NMR study of the transmission of electronic effects in triarylantimony and triarylbismuth compounds. A comparison with the nitrogen- and carbon-containing analogues Pages 185-200 S. I. Pombrik, D. N. Kravtsov, B. A. Kvasov, E. I. Fedin

Molecular orbitals and photoelectron spectra of some titanium(IV) organometallic compounds Pages 201-210 Mario Basso-Bert, Patrick Cassoux, Francois Crasnier, Danièle Gervais, Jean-Francois Labarre, Philippe De Loth

Thermal decomposition of dicyclopentadienylarylvanadium compounds Pages 211-218 C. P. Boekel, A. Jelsma, J. H. Teuben, H. J. De Liefde Meijer

(Diethyl muconate)(1,4-diaza-1,3-diene)carbonyliron complexes: syntheses, spectra, and structure Pages 219-233 Marco A. De Paoli, Hans-Werner Frühauf, Friedrich-Wilhelm Grevels, Ernst A. Koerner Von Gustorf, Werner Riemer, Carl Krüger

Kinetic studies and mechanism of triiron dodecacarbonyl reactions : I. Nucleophilic substitution in triiron dodecacarbonyl by triphenylphosphine in benzene Pages 235-239 Rattan Kumar

Reduction—complexation des sulfures de phosphines par les fer-carbonyles Pages 241-249 Francois Mathey, Georges Muller

Molecular and crystal structure of (+)-tetracarbonyl(methyl-1-naphthylphenylgermyl)-cobalt Pages 251-258 Francoise Dahan, Yves Jeannin

Formation of a novel alkylcobalt dimer Pages 259-264 Lynn Salisbury, H. W. Whitlock Jr.

Some reactions of allene and acetylenes with vinylplatinum and methylpalladium complexes Pages 265-279 H. C. Clark, C. R. C. Milne, C. S. Wong

Issue 3, Pages 289-405 (1977)

A cyclopropylplatinum to π-allylplatinum rearrangement Pages C52-C54 Ralph L. Phillips, Richard J. Puddephatt

Synthesis and x-ray structure of the anion tetra-μ-hydridodecacarbonyl-triangulo-trirhenate(1-) Pages C49-C51 G. Ciani, D. D'Alfonso, M. Freni, P. Romiti, A. Sironi, A. Albinati

Subject index Pages C59-C64

Synthesis of sym-polymethylcobalticenium salts Pages C55-C56 A. N. Nesmeyanov, R. B. Materikova, I. R. Lyatifov, T. Kh. Kurbanov, E. V. Leonova, N. S. Kochetkova

Regiospecific and stereoselective syntheses of hydroxycyclohexyltriphenyltin compounds Pages C41-C45 Richard H. Fish, Bruce M. Broline

Exchange and addition reactions involving tin—allyl compounds Pages C46-C48 Michael F. Fishwick, Malcolm G. H. Wallbridge

Author index Pages C57-C58

Umsetzung von metall- und metalloidverbindungen mit mehrfunktionellen molekülen : X. N-alkyl-N-ω-cyanoalkyl-amino(diorganyl)borane Pages 289-298 Anton Meller, Walter Maringgele, Franz J. Hirninger

The preparation and crystal structure of bis(μ-N,N′-diethylethylenediamido)bis(dihydridoaluminum)hydridoaluminum, HAl[(EtN(CH2)2NEt)AlH2]2, and its chlorinated derivative, (H0.85Cl0.15)Al[(EtN(CH2)2NEt)AlH(H0.7Cl0.3)]2 Pages 301-308 G. Perego, G. Del Piero, M. Corbellini, M. Bruzzone

Bis(pentachlorophenyl)thallium(III) compounds Pages 309-313 P. Royo, R. Serrano

Lewis acidity of organosilicon acetates Pages 315-321 D. P. Graddon, B. A. Rana

Rates of base-catalysed cleavage of pyridyl-, quinolyl-, picolyl- and (quinolylmethyl)-trimethylsilanes Pages 323-332 Alfred Fischer, Michael W. Morgan, Colin Eaborn

Die kristallstruktur des monoklinen hexamethylcyclotristannathians Pages 333-338 Hans-Jürgen Jacobsen, Bernt Krebs

Products of the reaction of Re2(CO)10 with methanolic KOH. The crystal and molecular structure of the trimethylbenzylammonium salt of hexa-μ2-hydridodecacarbonyl-tetrahedro-tetrarhenate(2—) Pages 339-348 Gianfranco Ciani, Angelo Sironi, Vincenzo G. Albano

The reaction between organosilyl derivatives of (η5-C5H5)Fe(CO)2 and triphenyl phosphite. New evidence for ortho-metalated phosphite ligands Pages 349-353 Genevieve Cerveau, Ernesto Colomer, Robert Corriu

NMR study of the photochemical reaction of (η5-C5H5)Fe(CO)2Me with P, As, Sb, S and N donor ligands Pages 355-361 Christina R. Folkes, Antony J. Rest

Interaction of electroneutral benzenecyclopentadienyliron with halogen derivatives Pages 363-370 A. N. Nesmeyanov, N. A. Vol'kenau, V. A. Petrakova

On the mechanism of acidic hydrogen isotopic exchange in σ-benzyl-π-cyclopentadienyliron dicarbonyl Pages 371-373 T. Yu. Orlova, V. N. Setkina, D. N. Kursanov

Structure cristalline et moleculaire du tetracarbonylcobaltatopyridine (N-(phenylamino)-α-methylbenzylidenimino-2-C,N) palladate(II), compose a liaison Pd---Co Pages 375-384 G. Le Borgne, S. E. Bouaoud, D. Grandjean, P. Braunstein, J. Dehand and, M. Pfeffer

Palladium-catalyzed phenylation of allylic 1-perfluoroalkyl alcohols Pages 385-387 Konrad Von Werner

Röntgenstrukturanalyse von chloro-(1—3-η-1,2-dimethylallyl)-N-(3-picolin)-palladium Pages 389-395 Hans Anton Graf, Rudolf Hüttel, Günter Nagorsen, Bernhard Rau

Bond lengths in platinum(II) and platinum(IV) complexes. Crystal and molecular structure of -tetrachlorobis(triethylphosphine) platinum(IV) Pages 397-405 Peter B. Hitchcock, Barbara Jacobson, Alan Pidcock